Ultrashort pulses at 920 nm are a highly desired light source in two-photon microscopy for the efficient excitation of green fluorescence protein. Although Nd^{3 +} -doped fibers have been utilized for 920-nm ultrashort pulse generation, the competitive amplified spontaneous emission (ASE) at 1.06 μm remains a significant challenge in improving their performance. Here, we demonstrate a coordination engineering strategy to tailor the properties of Nd^{3 +} -doped silica glass and fiber. By elevating the covalency between Nd^{3 +} and bonded anions via sulfur incorporation, the fiber gain performance at 920 nm is enhanced, and 1.06-μm ASE intensity is suppressed simultaneously. As a result, the continuous-wave laser efficiencies and signal-to-noise ratio at 920 nm by this fiber are significantly enhanced. Importantly, the stable picosecond pulses at 920 nm are produced by a passive mode-locking technique with a fundamental repetition rate up to 207 MHz, which, to the best of our knowledge, is the highest reported repetition rate realized by Nd^{3 +} -doped silica fibers. The presented strategy enriches the capacity of Nd^{3 +} -doped silica fiber in generating 920-nm ultrashort pulses for application in biophotonics, and it also provides a promising way to tune the properties of rare-earth ion-doped silica glasses and fibers toward ultrafast lasers.

A large-mode-area (LMA) ytterbium-doped photonic crystal fiber (PCF) with core NA of 0.034 and core diameter of 50 μm was made by the stack-and-draw technique. The core is formed by Yb³⁺/Al³⁺/F /P⁵⁺ co-doped silica glass containing 0.09 mol% Yb₂O₃ with an absorption coefficient at 976 nm up to 3.2 dB/m. The core glass with homogeneous distribution of Yb³⁺ ions and refractive index difference of 4 × 10 ⁴ compared with pure silica was prepared by the sol-gel method and heat homogenization at 2000°C. Laser power amplification of this LMA PCF was studied using a seed source of 21 ps pulse duration and 48.7 MHz repetition rate at 1030 nm wavelength. With pump power of 520 W, a maximum 272 W (266 kW peak power) quasi-single-mode laser output with M² of 2.2 was achieved in a 4.7 m fiber length bent at a diameter of 47 cm with slope efficiency of 52%, and no obvious mode instability, stimulated Raman scattering, or thermal damage on the end facet of the fiber were observed.

A large-mode-area neodymium-doped silicate photonic bandgap fiber was theoretically designed and experimentally demonstrated. The relative index step between the high-index rods and the background glass was ～0.5%, which is the lowest cladding index difference reported on rare-earth-doped all-solid photonic bandgap fibers to our knowledge. An output power of 3.6 W with a slope efficiency of 31% was obtained for a 100-cm-long fiber.

High flatness, wide bandwidth, and high-coherence properties of supercontinuum (SC) generation in fibers are crucial in many applications. It is challenging to achieve SC spectra in a combination of the properties, since special dispersion profiles are required, especially when pump pulses with duration over 100 fs are employed. We propose an all-solid microstructured fiber composed only of hexagonal glass elements. The optimized fiber possesses an ultraflat all-normal dispersion profile, covering a wide wavelength interval of approximately 1.55 μm. An SC spectrum spanning from approximately 1030 to 2030 nm (corresponding to nearly one octave) with flatness <3 dB is numerically generated in the fiber with 200 fs pump pulses at 1.55 μm. The results indicate that the broadband ultraflat SC sources can be all-fiber and miniaturized due to commercially achievable 200-fs fiber lasers. Moreover, the SC pulses feature high coherence and a single pulse in the time domain, which can be compressed to 13.9-fs pulses with high quality even for simple linear chirp compensation. The Fourier-limited pulse duration of the spectrum is 3.19 fs, corresponding to only 0.62 optical cycles.

We produce a maximum 1.45 W laser output at 1064 nm using a neodymium-doped silicate glass fiber that has a rectangular core with dimensions of ～6.3 μm×31.5 μm. The measured divergence angles of the output laser in two dimensions are 3.22° and 1.76°, respectively. The output power is stable and limited only by the available pump power.

Yb-doped silica glasses containing low, medium, and high content of OH are prepared through nanoporous glass sintering technology. High-OH sample exhibits better X-ray irradiation resistivity than low- and medium-OH samples. After irradiation, OH content of low- and medium-OH samples increases 37.5% and 11%, respectively; in contrast, OH content of high-OH sample decreases dramatically. The different OH content changes among the samples are discussed regarding the proposed inter-conversion reactions involving Si-H and Si-OH during the irradiation.